Crystal structure of bis(acetonitrile-κN)bis(4-benzoylpyridine-κN)bis(thiocyanato-κN)cobalt(II)
نویسندگان
چکیده
The crystal structure of the title compound, [Co(NCS)2(C2H3N)2(C12H9NO)2], consists of cobalt(II) cations that are octa-hedrally coordinated by the N atoms of two terminal thio-cyanate anions, two aceto-nitrile mol-ecules and two 4-benzoyl-pyridine ligands. The discrete complexes are located on centres of inversion. They are connected by weak inter-molecular C-H⋯O and C-H⋯S hydrogen-bonding inter-actions between one of the pyridine H atoms and the carbonyl O atom, and between one of the methyl H atoms of the aceto-nitrile mol-ecule and the thio-cyanate S atoms into layers parallel to (101). No pronounced inter-molecular inter-actions are observed between these layers.
منابع مشابه
Crystal structure of bis(4-benzoylpyridine-κN)bis(methanol-κO)bis(thiocyanato-κN)cobalt(II)
The crystal structure of the title compound, [Co(NCS)2(C12H9NO)2(CH3OH)2], consists of cobalt(II) cations that are octa-hedrally coordinated by two N-terminal bonding thio-cyanato anions, two methanol mol-ecules and two 4-benzoyl-pyridine ligands into discrete complexes that are located on centres of inversion. These complexes are further linked by O-H⋯O hydrogen bonding between the hy-droxy H ...
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عنوان ژورنال:
دوره 73 شماره
صفحات -
تاریخ انتشار 2017